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Adsorption studies of Mo and V onto ferrihydrite

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Brinza,  L.
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Benning,  Liane G.
0 Pre-GFZ, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;

Satham,  P. J.
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Citation

Brinza, L., Benning, L. G., Satham, P. J. (2008): Adsorption studies of Mo and V onto ferrihydrite. - Mineralogical Magazine, 72, 1, 385-388.
https://doi.org/10.1180/minmag.2008.072.1.385


Cite as: https://gfzpublic.gfz-potsdam.de/pubman/item/item_806905
Abstract
In this paper, the kinetics of Mo and V (100 mu M) uptake oil ferrihydrite (FHY) were evaluated in batch. mono-sorbate systems at pH between 4 and 9, and in bi-sorbate systems in the presence of P (100 mu M) at pH 7. In the Mo and V single-sorbate experiments, 100% adsorption was observed at pH values below 6 and 9, respectively. Above the point of zero charge (PZC = 7.97) of FHY, the adsorption efficiency for Mo dropped dramatically (20% at pH 8) while V showed high uptake efficiencies even at pH 9 (60% efficiency). The results from the bi-sorbate experiments (Mo-P and V-P) showed that at pH 71 P out-competed (97%) Mo for binding sites on FHY, while in the V-P binary system only similar to 44% of the binding sites are occupied by P with the remaining sites being occupied by V.