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  Boiling effects on trace element and sulfur isotope compositions of sulfides in shallow-marine hydrothermal systems: Evidence from Milos Island, Greece

Schaarschmidt, A., Haase, K. M., Klemd, R., Keith, M., Voudouris, P. C., Alfieris, D., Strauss, H., Wiedenbeck, M. (2021): Boiling effects on trace element and sulfur isotope compositions of sulfides in shallow-marine hydrothermal systems: Evidence from Milos Island, Greece. - Chemical Geology, 583, 120457.
https://doi.org/10.1016/j.chemgeo.2021.120457

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Schaarschmidt, Anna1, 2, Autor
Haase, Karsten M.1, 2, Autor
Klemd, Reiner1, 2, Autor
Keith, Manuel1, 2, Autor
Voudouris, Panagiotis C.1, 2, Autor
Alfieris, Dimitrios1, 2, Autor
Strauss, Harald1, 2, Autor
Wiedenbeck, Michael2, 3, Autor              
Affiliations:
1External Organizations, ou_persistent22              
2GFZ SIMS Publications, Deutsches GeoForschungsZentrum, Potsdam, ou_1692888              
33.1 Inorganic and Isotope Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum, ou_146040              

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Schlagwörter: Trace elements, Hydrothermal systems, Epithermal ore deposits, Boiling, Pyrite, Sulfur fugacity, Isotopes
 Zusammenfassung: Boiling is a crucial process triggering ore formation in magmatic-hydrothermal systems and controlling the enrichment of precious and rare metal(loid)s in epithermal-porphyry mineralizations. Steep physicochemical gradients during boiling of hydrothermal fluids at shallow water depths caused metal(loid) precipitation along a 3 km long Pb-Zn-Ag vein system on Milos Island in the South Aegean Volcanic Arc. We present new trace element and Pb, Sr, and S isotope data from sulfides providing insights into the diversity of mineralization processes in shallow-marine hydrothermal systems. Lead and Sr isotope compositions of sulfides and sulfates reflect the mixing of fluids that reacted with metamorphic basement and the volcanic host rocks, whereas some of the S were derived from seawater. Investigation of mineralized samples along the Kondaros-Vani fault zone revealed distinct chemical variations that represent a vertical profile through the boiling zone of a hydrothermal system. Boiling during fluid ascent at decreasing temperatures (230–150 ◦C) and sulfur fugacities triggered the precipitation of sulfides rich in Zn, Pb, Fe, Cu, Ag, Sb, and As, resulting in increasing Pb, Ag, and Sb contents with decreasing depth. A pyrite group with high Tl/Cu and low As/Sb ratios, as well as δ34SVCDT values reaching as low as -6‰, is interpreted as precipitating from high-Cl liquids that underwent vigorous boiling at deeper crustal levels subsequent to tectonic faulting. Condensation of vapor (high Hg, Bi, and As contents) and mixing with seawater (high Mo contents) in the shallow-marine subseafloor sequences at Vani caused Hg-Bi-Mo-As-rich mineralization similar to the active hydrothermal system at Milos.

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Sprache(n): eng - Englisch
 Datum: 2021-07-232021-07-282021
 Publikationsstatus: Final veröffentlicht
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: DOI: 10.1016/j.chemgeo.2021.120457
GFZPOF: p4 MESI
GFZPOFWEITERE: p4 T8 Georesources
 Art des Abschluß: -

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Titel: Chemical Geology
Genre der Quelle: Zeitschrift, SCI, Scopus
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Ort, Verlag, Ausgabe: -
Seiten: - Band / Heft: 583 Artikelnummer: 120457 Start- / Endseite: - Identifikator: CoNE: https://gfzpublic.gfz-potsdam.de/cone/journals/resource/journals68
Publisher: Elsevier