Deutsch
 
Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

 
 
DownloadE-Mail
  Reactivity of Calcite/Water-Interfaces (RECAWA) : Molecular level process understanding for technical applications

Stelling, J., Neumann, T., Kramar, U., Schäfer, T., Heberling, F., Winkler, B., Vinograd, V., Arbeck, D., Müller, H. S., Haist, M., Glowacky, J., Vucak, M., Fischer, U., Pust, C., Huber, J., Bosbach, D. (2010): Reactivity of Calcite/Water-Interfaces (RECAWA): Molecular level process understanding for technical applications. - In: Münch, U., Dransch, W. (Eds.), (GEOTECHNOLOGIEN Science Report ; 16), 76-95.
https://doi.org/10.2312/GFZ.gt.16.06

Item is

Dateien

einblenden: Dateien
ausblenden: Dateien
:
SR16_Mineral_06.pdf (Verlagsversion), 807KB
Name:
SR16_Mineral_06.pdf
Beschreibung:
-
Sichtbarkeit:
Öffentlich
MIME-Typ / Prüfsumme:
application/pdf / [MD5]
Technische Metadaten:
Copyright Datum:
-
Copyright Info:
-
Lizenz:
-

Externe Referenzen

einblenden:
ausblenden:
externe Referenz:
http://gfzpublic.gfz-potsdam.de/pubman/item/escidoc:42034 (Ergänzendes Material)
Beschreibung:
Gesamtausgabe GEOTECHNOLOGIEN Science Report No. 16

Urheber

einblenden:
ausblenden:
 Urheber:
Stelling, J.1, Autor
Neumann, T.1, Autor
Kramar, U.1, Autor
Schäfer, T.1, Autor
Heberling, F.1, Autor
Winkler, B.1, Autor
Vinograd, V.1, Autor
Arbeck, D.1, Autor
Müller, H. S.1, Autor
Haist, M.1, Autor
Glowacky, J.1, Autor
Vucak, M.1, Autor
Fischer, U.1, Autor
Pust, C.1, Autor
Huber, J.1, Autor
Bosbach, D.1, Autor
Affiliations:
1Mineral Surfaces - From Atomic Processes to Industrial Application : GEOTECHNOLOGIEN Science Report 16, GEOTECHNOLOGIEN Science Report, External Organizations, ou_28024              

Inhalt

einblenden:
ausblenden:
Schlagwörter: -
 Zusammenfassung: RECAWA intends to develop a fundamental understanding of the reactivity and dynamics of calcite surfaces during crystal growth in aquatic systems. Therefore, the calcite-water surface has been characterised at different hydrochemical conditions and surface diffraction measurements have been applied to probe if changes in zeta potential are accompanied by changes in the calcite-water interface structure. The interaction of calcite with Selenium is investigated in a mixed flow reactor (MFR) study which is accompanied by GI- EXAFS analyses to characterize the Se adsorption species. The interaction of calcite surfaces with phosphate and phosphonates is the focus of two subprojects. The sorption/precipitation mechanisms of PO43- and HPO32+, respectively, on different calcite powders (precipitated calcium carbonates and limestone powders) are investigated to determine sorption isotherms and phase transformations on the applied surfaces which is of great interest with regard to phosphate recycling and/or water treatment. Analytical work includes SEM, XRD and XAFS spectroscopy for a detailed characterisation of the calcite powders in different sections of the isotherms. Experimental investigations on the interaction of limestone powder and two superplasticizers have been conducted with regard to concreting. These experiments were done at alkaline conditions and lead to massive reactions and changes in the zeta potential of the solutions and limestone powder when superplasticizers added. Additional results of quantum-mechanical calculations and force-field modelling demonstrated that the Double Defect Method is able to quantitatively predict mixing properties of various isostructural binary and ternary carbonate solid solutions. In particular, low equilibrium retention levels of SO42- and SeO42- in carbonates imply that the reasonably large concentrations SO42- and SeO42- in carbonates reported in previous studies should be attributed to non-equilibrium entrapment effects. Data obtained from atomistic modelling complement our data determined using lab methods. Further experimental and analytical, work including in-situ AFM studies using Iceland spar single crystals, is in progress and will help to interconnect the present results of the sub-projects.

Details

einblenden:
ausblenden:
Sprache(n): eng - Englisch
 Datum: 2010
 Publikationsstatus: Final veröffentlicht
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: DOI: 10.2312/GFZ.gt.16.06
 Art des Abschluß: -

Veranstaltung

einblenden:

Entscheidung

einblenden:

Projektinformation

einblenden:

Quelle 1

einblenden:
ausblenden:
Titel: GEOTECHNOLOGIEN Science Report
Genre der Quelle: Reihe
 Urheber:
Münch, Ute1, Herausgeber
Dransch, Werner1, Herausgeber
Affiliations:
1 Mineral Surfaces - From Atomic Processes to Industrial Application : GEOTECHNOLOGIEN Science Report 16, GEOTECHNOLOGIEN Science Report, External Organizations, ou_28024            
Ort, Verlag, Ausgabe: Potsdam : GEOTECHNOLOGIEN Koordinierungsbüro
Seiten: 204 Band / Heft: 16 Artikelnummer: 6 Start- / Endseite: 76 - 95 Identifikator: ISSN: 1619-7399