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  Stable Isotope Signatures of Wood, its Constituents and Methods of Cellulose Extraction

Helle, G., Pauly, M., Heinrich, I., Schollaen, K., Balanzategui, D., Schürheck, L. (2022): Stable Isotope Signatures of Wood, its Constituents and Methods of Cellulose Extraction. - In: Siegwolf, R. T. W., Brooks, J. R., Roden, J., Saurer, M. (Eds.), Stable Isotopes in Tree Rings, (Tree Physiology book series ; 8), Cham : Springer International Publishing, 135-190.
https://doi.org/10.1007/978-3-030-92698-4_5

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 Creators:
Helle, G.1, Author              
Pauly, Maren1, Author              
Heinrich, Ingo1, Author              
Schollaen, Karina2, Author              
Balanzategui, Daniel1, Author              
Schürheck, Lucas1, Author              
Affiliations:
14.3 Climate Dynamics and Landscape Evolution, 4.0 Geosystems, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum, ou_146046              
2Deutsches GeoForschungsZentrum, ou_persistent13              

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 Abstract: In this chapter, we give some basic information on the chemical and isotopic properties of wood constituents and describe their relative contribution to the isotopic signature of wood. Based on these considerations we review studies that have compared stable isotope signals of wood with those of corresponding cellulose. We exemplify how relationships of wood-based tree-ring stable isotope sequences with climate can be affected by varying proportions of wood constituents like cellulose, lignin and extractives. A majority of benchmarking studies suggests that cellulose extraction may not be necessary. However, based upon existing research, a general statement cannot be made on the necessity of cellulose extraction. Changes in wood composition can particularly influence environmental signal strength during periods of low isotope variability. Cellulose extraction removes any effects from changing wood composition. We present the three established chemical approaches of extraction, outline how to test the purity of isolated cellulose and present user-friendly efficient experimental setups allowing to simultaneously process hundreds of samples in one batch. Further, we briefly address the analysis of stable isotopes of lignin methoxyl groups because of easy sample preparation and its potential additional value for studies on fossil wood.

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 Dates: 2022-06-072022
 Publication Status: Finally published
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 Identifiers: DOI: 10.1007/978-3-030-92698-4_5
GFZPOF: p4 T2 Ocean and Cryosphere
GFZPOFWEITERE: p4 T5 Future Landscapes
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Title: Stable Isotopes in Tree Rings
Source Genre: Book
 Creator(s):
Siegwolf, Rolf T. W.1, Editor
Brooks, J. Renée1, Editor
Roden, John1, Editor
Saurer, Matthias1, Editor
Affiliations:
1 External Organizations, ou_persistent22            
Publ. Info: Cham : Springer International Publishing
Pages: - Volume / Issue: - Sequence Number: - Start / End Page: 135 - 190 Identifier: ISSN: 1568-2544
ISBN: 978-3-030-92697-7
ISBN: 978-3-030-92698-4

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Title: Tree Physiology book series
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Pages: - Volume / Issue: 8 Sequence Number: - Start / End Page: - Identifier: -