Deutsch
 
Datenschutzhinweis Impressum
  DetailsucheBrowse

Datensatz

 
 
DownloadE-Mail
  An unusual paragenesis of diamond, graphite, and calcite: a Raman Spectroscopy study

Thomas, R., Rericha, A., Davidson, P., Beurlen, H. (2021): An unusual paragenesis of diamond, graphite, and calcite: a Raman Spectroscopy study. - Estudos Geológicos, 31, 2.
https://doi.org/10.18190/1980-8208/estudosgeologicos.v31n2p3-15

Item is

Externe Referenzen

einblenden:

Urheber

einblenden:
ausblenden:
 Urheber:
Thomas, R.1, Autor              
Rericha, Adolf2, Autor
Davidson, Paul2, Autor
Beurlen, Hartmut2, Autor
Affiliations:
13.6 Chemistry and Physics of Earth Materials, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum, ou_146036              
2External Organizations, ou_persistent22              

Inhalt

einblenden:
ausblenden:
Schlagwörter: Diamond, 13C-rich diamond, calcite, graphite, lonsdaleite, Raman spectroscopy
 Zusammenfassung: This work presents a study of an unusual synthetic diamond sample, where calcite is the main phase in addition to diamond. Using Raman spectroscopy it can be shown that in addition to diamond carbon forms four different generations: highly ordered graphite-II, lower ordered graphite-I as spandrel between different mineral grains, weakly-ordered carbonaceous material as graphite-III and the hexagonal diamond lonsdaleite (here graphite-IV) as last formation in calcite. Graphite-III can be found mainly in the calcite body. According to the fine dispersion of this carbonaceous material and the arrangement on grain boundaries, we assume that carbon was dissolved in the calcite melt, and that by the activated state of carbon in the calcite melt the formation of diamond is favored near 1760°C, and 6.8 GPa. Lonsdaleite as minor phase may have been formed as an longlived intermediate state under standard conditions between graphite and diamond. Evidence shows that there are two different lonsdaleite phases (possibly hexagonal and monocline) present. The prevailing diamond is characterized by the first-order Raman line at 1333 cm-1. However, there are also present diamonds with the first-order Raman line down to 1310.6 cm-1, corresponding to 13C = 0.511. Significantly there is the strong decrease of the optical damage threshold with increase of the 13C content.

Details

einblenden:
ausblenden:
Sprache(n): eng - Englisch
 Datum: 2021
 Publikationsstatus: Final veröffentlicht
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: DOI: 10.18190/1980-8208/estudosgeologicos.v31n2p3-15
GFZPOF: p4 T3 Restless Earth
OATYPE: OA other
 Art des Abschluß: -

Veranstaltung

einblenden:

Entscheidung

einblenden:

Projektinformation

einblenden:

Quelle 1

einblenden:
ausblenden:
Titel: Estudos Geológicos
Genre der Quelle: Zeitschrift, other, oa, Bronze OA
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: -
Seiten: - Band / Heft: 31 (2) Artikelnummer: - Start- / Endseite: - Identifikator: CoNE: https://gfzpublic.gfz-potsdam.de/cone/journals/resource/journal2_876
Publisher: Universidade Federal de Pernambuco