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Abstract:
Amorphous silica is a common precipitate in modern and ancient hot springs and in geothermal power plants, yet the corresponding precipitation rates and mechanisms are still highly debated, primarily due to the plethora of parameters that can affect the reactions in natural waters. Here, we report the results from a first ever industrial-scale time-resolved (1 day to 10 weeks) study of silica precipitation conducted at the Hellisheiði geothermal power plant (SW-Iceland). We show that such in-work pipelines of a geothermal power plant are ideal environments to investigate silica precipitation because the physicochemical conditions are well constrained and constantly monitored. Our results document that amorphous silica forms via two distinct precipitation modes: (1) the fast deposition of continuous botryoidal silica layers and (2) the growth of 3D fan- or ridge-shaped silica aggregates. The continuous layers grow by heterogeneous nucleation and subsequent surface controlled growth by monomer addition. In contrary, the 3D aggregates form through homogeneous nucleation of silica nano- and microparticles in solution, followed by deposition and cementation on the surface of the botryoidal layer. From the time-resolved data, silica precipitation rates of over 1 g m−2 day-1 are derived. Over time, this deposition of silica on pipelines and fluid handling equipment is detrimental to geothermal power production. Our data does not only help improve our understanding of silica precipitation from geothermal fluids, but the determined silica precipitation mechanisms and rates help improve mitigation strategies against silica scaling inside in-work geothermal power plants.
