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  The Furongian to Lower Ordovician Alum Shale Formation in conventional and unconventional petroleum systems in the Baltic Basin – A review

Schulz, H.-M., Yang, S., Schovsbo, N. H., Rybacki, E., Ghanizadeh, A., Bernard, S., Mahlstedt, N., Krüger, M., Amann-Hildebrandt, A., Krooss, B. M., Meier, T., Reinicke, A. (2021): The Furongian to Lower Ordovician Alum Shale Formation in conventional and unconventional petroleum systems in the Baltic Basin – A review. - Earth-Science Reviews, 218, 103674.
https://doi.org/10.1016/j.earscirev.2021.103674

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Item Permalink: https://gfzpublic.gfz-potsdam.de/pubman/item/item_5006662 Version Permalink: https://gfzpublic.gfz-potsdam.de/pubman/item/item_5006662_2
Genre: Journal Article

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 Creators:
Schulz, H.-M.1, Author              
Yang, Shengyu2, Author
Schovsbo, Niels H.2, Author
Rybacki, Erik3, Author              
Ghanizadeh, Amin2, Author
Bernard, Sylvain2, Author
Mahlstedt, Nicolaj1, Author              
Krüger, Martin2, Author
Amann-Hildebrandt, Alexandra2, Author
Krooss, Bernhard M.2, Author
Meier, Tobias2, Author
Reinicke, Andreas2, Author
Affiliations:
13.2 Organic Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum, ou_146041              
2External Organizations, ou_persistent22              
34.2 Geomechanics and Scientific Drilling, 4.0 Geosystems, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum, ou_146035              

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Free keywords: Black shale, Cambrian, Ordovician, Organic carbon, Petroleum, Uranium
 Abstract: The organic carbon-and uranium-rich, marine Alum Shale Formation in northwestern Europe (Middle Cambrian (Miaolingian) to Early Ordovician) was deposited in the Baltic Basin and surrounding areas. It is a proven source rock for conventional oil either in sandstones of Cambrian age or Ordovician and Silurian carbonates, and also contains a potential for shale oil and for biogenic or thermogenic shale gas. Despite the absence of higher land plant precursors, the primary Type II kerogen has an abnormally strong aromatic character at low thermal maturities due to α-particle bombardment by the elevated uranium content. The characteristic aromatic kerogen structure results in dead carbon formation and enhances hydrocarbon retention. As a consequence, effective petroleum expulsion is limited during maturation. The petroleum generation properties of the Alum Shale Formation changed over geological time due to the accumulated uranium irradiation. For thermally immature samples, high uranium content is positively correlated with high gas-oil ratios and the aromaticities of both the free hydrocarbons residing in the rock and the pyrolysis products from its kerogen. Such characteristics indicate that irradiation has had a strong influence on the overall organic matter composition and hence on the petroleum potential. At high uranium content, macromolecules are less alkylated than their less irradiated counterparts and oxygen containing-compounds are enriched. However, the kerogen structure was less altered during catagenesis (420–340 Ma bp) than at present, and thus calibration is needed to predict petroleum generation in time and space. In southern central Sweden biogenic methane in the Alum Shale Formation was formed during oil degradation after the Quaternary glaciation following bitumen impregnation generated from local magmatic Carboniferous – Permian intrusions. Consequently, the Alum Shale Formation includes a mixed shale oil/biogenic gas play that resembles the formation of biogenic methane in the Antrim Shale (Michigan Basin, United States). In the Alum Shale Formation, low salinity pore water created a subsurface aqueous environment, which was favourable for microbes that have the potential to form biogenic methane. The ability to generate biogenic methane from samples of the Alum Shale Formation in incubation experiments still exists today. The permeability coefficients of highly mature Alum Shale Formation from Bornholm Island (southern Baltic Sea) cover a broad range from sub-nanodarcy to microdarcy, depending on fluid type (i.e. gas vs. liquid), (in-situ) fluid content, anisotropy, pore pressure and effective stress conditions. In general, the primary high total organic carbon content was not significantly reduced at overmature stages, consistently with the high sorption capacities. The Alum Shale Formation is thus an attractive gas shale candidate from the perspective of gas generation and retention. The strength of the overmature Alum Shale Formation on Bornholm, which is mainly determined by mineral composition, porosity and spatial distribution of the constituents, is relatively low compared to other well-studied shale formations. Based on brittleness estimates, the Alum Shale Formation may be regarded as an unconventional reservoir rock of medium quality from the mechanical point of view.

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Language(s): eng - English
 Dates: 20212021
 Publication Status: Finally published
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1016/j.earscirev.2021.103674
GFZPOF: p4 T8 Georesources
 Degree: -

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Title: Earth-Science Reviews
Source Genre: Journal, SCI, Scopus
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Pages: - Volume / Issue: 218 Sequence Number: 103674 Start / End Page: - Identifier: CoNE: https://gfzpublic.gfz-potsdam.de/cone/journals/resource/journals104
Publisher: Elsevier