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DEAL Elsevier
Abstract:
A natural gem quality, inclusion-free, U-poor xenotime has been metasomatically altered at 900 °C and 500–1000 MPa in a series of alkali-bearing fluids including 2 N KOH, 2 N NaOH, Na2Si2O5 + H2O, and NaF + H2O to which UO2 and SiO2 have been added. All experiments were buffered to CO2-CO-graphite with the exception of the NaF + H2O experiment at 900 °C and 500 MPa, which was buffered to magnetite-hematite. With the exception of the Na2Si2O5 + H2O experiment, the xenotime reacted with the fluid tried in all of the remaining experiments to varying degrees. The xenotime showed the greatest degree of reactivity in the two NaF + H2O experiments tried. This reactivity takes the form of a coupled dissolution-reprecipitation reaction, which involves enriching reacted areas of the xenotime in U + Si as well as remobilizing the HREE in these areas inherent to the original xenotime. One result was the formation of alternating bands of Y-rich and HREE- + U-rich bands in the NaF + H2O experiment when the system was oxidized, which are presumed to have formed due a combination of simple chemical zoning coupled with diffusion and coupled dissolution-reprecipitation in the altered areas of the xenotime. A total lack of fluid and mineral inclusions on the nano-scale, as well as no disturbances in the crystal lattice in the reacted areas of the xenotime under HRTEM imaging, indicated that total recrystallization of the reacted areas took place during the course of the NaF + H2O experiment. The results of these experiments has important implications for the metasomatic resetting of the xenotime geochromometer in the presence of alkali-bearing fluids, which would potentially allow metasomatised xenotime to time and record metasomatic events affecting the rock.
