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  Bulk rock geochemical and mineralogical characterisation of clay-rich sediments from drill core analysis of the Staffelegg Formation

Bonitz, M., Hennig, T., Schleicher, A. M., Jaeggi, D., Stammeier, J. A., Ostertag-Henning, C., Kühn, M. (2025): Bulk rock geochemical and mineralogical characterisation of clay-rich sediments from drill core analysis of the Staffelegg Formation. - Applied Geochemistry, 186, 106389.
https://doi.org/10.1016/j.apgeochem.2025.106389

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 Creators:
Bonitz, Marie1, 2, Author              
Hennig, Theresa1, Author              
Schleicher, Anja Maria3, Author              
Jaeggi, David4, Author
Stammeier, Jessica Alexandra3, Author              
Ostertag-Henning, Christian4, Author
Kühn, M.1, Author              
Affiliations:
13.4 Fluid Systems Modelling, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum, ou_146047              
2Submitting Corresponding Author, Deutsches GeoForschungsZentrum, ou_5026390              
33.1 Inorganic and Isotope Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum, ou_146040              
4External Organizations, ou_persistent22              

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Free keywords: Opalinus Clay Mont Terri Nuclear waste disposal Mineralogical and geochemical alteration
 Abstract: The long-term integrity of argillaceous formations as host rocks for deep geological disposal of nuclear waste depends significantly on hydrogeological factors. A 58 m long borehole was drilled at the Mont Terri Rock Laboratory (Switzerland) from the Opalinus Clay through the entire underlying Staffelegg Formation, which includes two water-bearing sections. Groundwater was found locally in the Beggingen and Rietheim Members, otherwise known as Gryphaea Limestone and Posidonia Shale, respectively. We want to identify indicators to determine the impact of groundwater flow in clay- and carbonate-rich sediments by characterising mineralogical and geochemical alteration. The groundwater influence is restricted to the water-bearing zones and can be identified by fractures and calcite veins. Additional indicators like mineral assemblage, rock geochemistry and the combination of different redox proxies, show constrained groundwater influence in the clay-rich areas. To investigate in particular the water-bearing horizons on a smaller scale (mm-m) would help to detect further alteration and mobilisation features.

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 Dates: 20252025
 Publication Status: Finally published
 Pages: -
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 Rev. Type: -
 Identifiers: DOI: 10.1016/j.apgeochem.2025.106389
GFZPOF: p4 T8 Georesources
GFZPOFCCA: p4 CARF NucRep
OATYPE: Hybrid - DEAL Elsevier
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Title: Applied Geochemistry
Source Genre: Journal, SCI, Scopus
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Pages: - Volume / Issue: 186 Sequence Number: 106389 Start / End Page: - Identifier: CoNE: https://gfzpublic.gfz-potsdam.de/cone/journals/resource/journals33
Publisher: Elsevier