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Barite, Anhydrite and Gypsum Reference Materials forIn SituOxygen and Sulfur Isotope Ratio Measurements

Authors
/persons/resource/binli

Li,  Bin
3.1 Inorganic and Isotope Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

/persons/resource/michawi

Wiedenbeck,  Michael
3.1 Inorganic and Isotope Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

/persons/resource/couffig

Couffignal,  F.
3.1 Inorganic and Isotope Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

Álvarez‐Valero,  Antonio M.
External Organizations;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

Bao,  Hui‐Ming
External Organizations;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

Fan,  Chang‐Fu
External Organizations;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

Han,  Juan
External Organizations;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

Jin,  Gui‐Shan
External Organizations;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

Peng,  Yong‐Bo
External Organizations;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

/persons/resource/marcin

Syczewski,  Marcin D.
3.5 Interface Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

Tait,  Kimberly T.
External Organizations;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

/persons/resource/fwilke

Wilke,  F.
3.1 Inorganic and Isotope Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

Wortmann,  Ulrich G.
External Organizations;
GFZ SIMS Publications, Deutsches GeoForschungsZentrum;

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Citation

Li, B., Wiedenbeck, M., Couffignal, F., Álvarez‐Valero, A. M., Bao, H., Fan, C., Han, J., Jin, G., Peng, Y., Syczewski, M. D., Tait, K. T., Wilke, F., Wortmann, U. G. (2024): Barite, Anhydrite and Gypsum Reference Materials forIn SituOxygen and Sulfur Isotope Ratio Measurements. - Geostandards and Geoanalytical Research, 48, 1, 179-205.
https://doi.org/10.1111/ggr.12533


Cite as: https://gfzpublic.gfz-potsdam.de/pubman/item/item_5024017
Abstract
Secondary ion mass spectrometry was used to test the d18O and d34S nanogram-scale homogeneity of a suite of candidate sulfate minerals, ultimately selecting three barite, two anhydrite, and two gypsum samples from the Royal Ontario Museum that have repeatabilities for their SIMS measurements of better than 0.39‰ and 0.37‰ (1s) for oxygen and sulfur isotope ratios, respectively. Metrological splits of each of the seven materials were sent to multiple gas source isotope ratio mass spectrometry laboratories in order to establish their absolute 18O/16O and 34S/32S ratios. The inter-laboratory results of GS-IRMS analyses yielded reasonably narrow ranges in d18OVSMOW, whereas larger variations in d34SVCDT values were found between the results from the gas source laboratories. All samples have good reproducibility within laboratories of GS-IRMS 103d18O values of between 0.24‰ and 0.44‰ (1s). The reproducibility within laboratories of GS-IRMS 103d34S values range from 0.07‰ to 0.99‰ (1s). Here we also discuss some of the current analytical limitations affecting these isotope-mineral systems. A total of 256 metrological splits have been prepared from each of these seven materials; these aliquots will be made available to the global geochemical community.