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NSO-compounds in oil-bearing fluid inclusions revealed by FT-ICR-MS in APPI (+) and ESI (−) modes: A new method development

Urheber*innen
/persons/resource/yhan

Han,  Yufu
3.2 Organic Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;

/persons/resource/noah

Noah,  Mareike
3.2 Organic Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;

/persons/resource/volue

Lüders,  Volker
3.2 Organic Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;

/persons/resource/horsf

Horsfield,  B.
External Organizations;

/persons/resource/kama

Mangelsdorf,  Kai
3.2 Organic Geochemistry, 3.0 Geochemistry, Departments, GFZ Publication Database, Deutsches GeoForschungsZentrum;

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5003577.pdf
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Zitation

Han, Y., Noah, M., Lüders, V., Horsfield, B., Mangelsdorf, K. (2020): NSO-compounds in oil-bearing fluid inclusions revealed by FT-ICR-MS in APPI (+) and ESI (−) modes: A new method development. - Organic Geochemistry, 149, 104113.
https://doi.org/10.1016/j.orggeochem.2020.104113


Zitierlink: https://gfzpublic.gfz-potsdam.de/pubman/item/item_5003577
Zusammenfassung
The origins of hydrocarbons occurring in oil-bearing fluid inclusions (FIs) have been studied in detail over the last four decades, but very little is known about co-occurring nitrogen, sulfur and oxygen (NSO)-containing compounds. Here, we outline a new method for gathering valuable information on NSO-compounds using the Fourier Transform-Ion Cyclotron Resonance-Mass Spectrometry (FT-ICR-MS) in combination with Atmospheric Pressure Photoionization in positive ion mode (APPI (+)) and Electrospray Ionization in negative ion mode (ESI (−)). A key element was to develop a rigorous acid-free cleaning protocol to make oil inclusions from a broad range of host materials accessible to the very sensitive FT-ICR-MS technique. Although oil contamination from surrounding organic matter could not be entirely eliminated, the procedure enables distinction of external contaminants and identification of affected NSO-compound classes allowing a conditional interpretation of the FT-results of FI samples, especially for compounds measured in the APPI (+) mode. First insights into the high molecular weight hydrocarbons and NSO-compounds in FI oils are presented here using examples from Germany, Tunisia, Pakistan and Mexico.